Specifies a starting guess for the structure coefficients. If this card is not
provided, and no guess specified by START, the perfect-pairing mode of
spin coupling is assumed for the spatial configuration having the least
number of doubly occupied orbitals.
Note that the definition of structures depends on the value of SPINBASIS. Doubly occupied
orbitals occur first in all configurations, and the spin eigenfunctions are based on the singly
occupied orbitals being in ascending order.